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Lithium‐air battery has become a sensible electrochemical energy innovation; yet a substantial overpotential is generally observed, due to the protecting nature of the discharge product Li2O2 that hinders the reaction kinetics and gadget efficiency. Here, in‐situ doping of Li2O2 by choose metal ions is discovered to considerably enhance the LAB performance, and Co2+ stands apart as one of the most efficient dopant among the collection. Outcomes from this research highlight the value of in situ electrochemical doping of the discharge product in boosting the efficiency of LAB.
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