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Cations and Anion - Europe PMC

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Last Updated: 16 January 2022

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Anion-cation interactions in a series of salts with substituted Hphen, Hbpy and H2bpy cations and [W(CN)8]4- anion: polymer with "super-short" N-H⋯N hydrogen bridges containing exclusively anions and H.

The ten ion-pairs of [W 8] 4- with substituted Hphen and H n bpy n + were isolated, and the spectroscopic properties of these salts are investigated. n + cation are three salts with dimethyl-substituted H n bpy n + cation were structurally characterized. One of the anion's cyanido ligands, which is in the CNH form, is found in the salt's structure with H2 bpy. [W 8] 4- ] This situation is very unique, as well as the emergence of two water double bridges by water molecules in [W 8 ] 4-.

Source link: https://europepmc.org/article/MED/34842868

* Please keep in mind that all text is summarized by machine, we do not bear any responsibility, and you should always check original source before taking any actions

* Please keep in mind that all text is summarized by machine, we do not bear any responsibility, and you should always check original source before taking any actions