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Cathode Material - DOAJ

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Last Updated: 27 September 2022

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Hydrogen reduction of spent lithium-ion battery cathode material for metal recovery: Mechanism and kinetics

Hydrogen reduction is proving to be a cost-effective method for recycling lithium-ion battery cathode materials. The hydrogen reduction process could be broken into three key stages: deposition of cathode materials, reduction of the resultant nickel and cobalt oxide reduction, and reduction of LiMnO2 and cobalt oxides can be broken down into three key stages. The hydrogen reduction rate with increasing temperature increased, and 800 b0C was the ideal temperature for separating the magnetic Ni-Co alloy from the non-magnetic manganese oxide particles.

Source link: https://doi.org/10.3389/fchem.2022.1019493


A Minireview on the Regeneration of NCM Cathode Material Directly from Spent Lithium-Ion Batteries with Different Cathode Chemistries

However, none of the existing research into regenerated lithium manganese cobalt oxide cathode materials from spent LIBs that contained other than NCM cathodes, but also commonly used commercial cathode materials such as LiCoO 2, LiFePO 4, LiMn 2 O 4, etc. This review explores the methods and techniques used to produce LiNi x Co y Mn z O 2 cathode active compounds directly from several commonly used and various types of mixed-cathode products. The article discusses the different methods and processes of recovering LiNi x Co Mn z O 2 cathode active materials directly from some specific cathode resins and the mixed-cathode scraps of spent LIBs without preliminary separation.

Source link: https://doi.org/10.3390/inorganics10090141


Laboratory X-ray Microscopy Study of Microcrack Evolution in a Novel Sodium Iron Titanate-Based Cathode Material for Li-Ion Batteries

Battery life Long-term battery results are highly dependent on the 3D morphology of electrode materials. The use of sophisticated in situ and operando techniques is required to obtain a comprehensive understanding of electrode materials' fracture mechanics in micro- and nanoscale dimensions. Using laboratory-based in situ and operando X-ray microscopy, we investigate the morphology of Na 0. 9 Fe 0. 45 O 4 sodium iron titanate cathode material in Li-ion batteries. We'll end by discussing the operando cells' design for the study of electrochemical reactions.

Source link: https://doi.org/10.3390/cryst12010003


Highly Loaded and Binder-Free Molybdenum Trioxide Cathode Material Prepared Using Multi-Arc Ion Plating for Aqueous Zinc Ion Batteries

Due to the benefits of safety and an abundant zinc supply, Aqueous zinc-ion batteries are becoming more popular as the use of energy storage systems rises. Following 500 cycles at 1000 mA g u22121 latest density, the capacity retention rate increased by 92. 4 percent after 100 cycles, as well as an outstanding cycling result of 109. 8 mAh g u22121 current density. When compared to a cell made from commercial MoO 3 using conventional slurry-based electrode technology, it was found that CFC-loaded u03b1-MoO3 cathode resin had noticeably enhanced electrochemical results. The results show that the highly packed cathode film with a high charge density could be used for future flexible device assembly and applications.

Source link: https://doi.org/10.3390/ma15175954


Synthesis, Structure, and Sodium Mobility of Sodium Vanadium Nitridophosphate: A Zero-Strain and Safe High Voltage Cathode Material for Sodium-Ion Batteries

The cubic symmetry with the P213 space group is confirmed by X-ray diffraction and Rietveld refinement. The lower experimental capacity compared to the theoretical one reveals the poor availability of sodium cations in the Na2 and Na3 sites as the primary reason for the lower experimental capacity versus the theoretical one.

Source link: https://doi.org/10.3390/en10070889


Eggshell-Membrane-Derived Carbon Coated on Li 2 FeSiO 4 Cathode Material for Li-Ion Batteries

The Lithium iron orthosilicate cathode can be made by the polyol-assisted ball milling process with the addition of carbon derived from eggshell membrane for improving inherent poor electronic conduct. The diffraction peaks were found without the presence of any further impure phase in the powder X-ray diffraction pattern. The carbon coating on the LFS, the porous nature of carbon, and the atom arrangements are shown by electron microscopy images clearly. The conversion of the anodic to the cathodic peak current was calculated as 1. 03, indicating that the materials have good reversibility, according to the cyclic voltammetry graph. The material has a discharge specific capacity of 194 mAh g u22121 for the first cycle, with capacity retention and an average coulombic yield of 94. 7% and 98. 5% up to 50 cycles in comparison to 50 cycles.

Source link: https://doi.org/10.3390/en13040786


Defect Process, Dopant Behaviour and Li Ion Mobility in the Li 2 MnO 3 Cathode Material

Lithium manganite, Li 2 MnO 3, is a popular cathode material for rechargeable lithium ion batteries due to its high capacity, low cost, and low toxicity. The Li Frenkel, which is essential for the establishment of Li vacancies in vacancy-assisted Li ion diffusion, is considered to be the most favourable intrinsic defect. A Li ion can be extracted quickly from this powder thanks to its low activation energy of 0. 44 eV.

Source link: https://doi.org/10.3390/en12071329


Operando XAFS and XRD Study of a Prussian Blue Analogue Cathode Material: Iron Hexacyanocobaltate

Operando X-ray diffraction and X-ray absorption fine structure assisted by chemometric techniques investigated potassium iron hexacyanocobaltate's reversible electrochemical lithiation of potassium iron hexacyanocobaltate. These investigations revealed that FeCo includes iron as the main electroactive site. An independent but interrelated analysis technique provides a timely snapshot of the study's progress and provides a realistic and integrated view of the current system.

Source link: https://doi.org/10.3390/condmat3040036


First-Principles Study of the Impact of Grain Boundary Formation in the Cathode Material LiFePO 4

Although the grain boundary in LiFePO 4 has desirable structural and bonding characteristics, the parallel boundary in FePO 4 needs to be yet optimized to accommodate a cost-effective Li diffusion study, according to the results.

Source link: https://doi.org/10.3390/condmat4030080


Atomic Layer Deposition of Lithium–Nickel–Silicon Oxide Cathode Material for Thin-Film Lithium-Ion Batteries

Due to their large capacity, lithium nitium nickelate and its components based on it are useful positive electrode materials for lithium-ion batteries. The results of atomic layer deposition of lithium hexazide and bis nickel are shown in this paper, as precursors and remote oxygen plasma as a counter-reagent. In a single supercycle, the pulse ratio of LiHMDS/Ni 2 precursors varied from 1/1 to 1/10. Silicon was discovered in the deposited films, and after annealing, crystalline Li 2 SiO 3 and Li 2 Si 2 O 5 were made at 800 °u00b0C.

Source link: https://doi.org/10.3390/en13092345

* Please keep in mind that all text is summarized by machine, we do not bear any responsibility, and you should always check original source before taking any actions

* Please keep in mind that all text is summarized by machine, we do not bear any responsibility, and you should always check original source before taking any actions