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Cathode Material - Astrophysics Data System

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Last Updated: 27 January 2023

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A kinetic study on cobalt-free high-nickel layered oxide cathode materials for practical lithium-ion batteries

The battery industry is raising the cost of lithium-ion batteries, while cathode products' high cost is anticipated to be the primary reason for the rise in lithium-ion battery prices. We review the ICE of cobalt-free LiNiO 2 systematically, considering the kinetic factors that control this phenomenon in terms of primary particle size, cell operating temperature, and current density. A connection between Li + diufb00usion kinetics and residual lithium content is also discussed, which is useful for practical cells.

Source link: https://ui.adsabs.harvard.edu/abs/2023JPS...55832633K/abstract


Amino-Acid-Substituted Perylene Diimide as the Organic Cathode Materials for Lithium-Ion Batteries

Organic compounds can be added to electrode materials instead of costly inorganic-based materials, making it one of the most cost-effective cost savings and green engineering initiatives. In this work, perylene diimide derivatives substituted with amino acids displayed the characteristics of redox-active organic compounds and were thus used as cathode materials of lithium-ion batteries.

Source link: https://ui.adsabs.harvard.edu/abs/2023Mate...16..839S/abstract


Pressure effect on the structural, electronic, and magnetic properties of the battery cathode material LiMn 2 O 4 : An ab-initio study

LiMn 2 O 4 is a battery cathode material with desirable characteristics such as low cost, low toxicity, a rich natural abundance of Mn, and environmental compatibility. In addition, the enthalpy of cubic and orthorhombic structures under low and high pressure conditions was investigated, indicating that no cubic to orthorhombic phase transition exists in any of the investigated pressure range, nor is a magnetic cubic phase transition possible.

Source link: https://ui.adsabs.harvard.edu/abs/2023JPCS..17511198S/abstract


Lithium-rich antiperovskite (Li 2 Fe)SeO: A high-performance cathode material for lithium-ion batteries

Proposing candidates for lithium-ion batteries with high energy density are Lithium-rich antiperovskite cathode materials with cationic and anionic redox bi-functionality, which are promising candidates for lithium-ion batteries with high energy density. Electrochemical investigations of SeO-based cathodes demonstrate a multi-step redox reaction that involves electrochemical reactions of cationic Fe and anionic Se. The material is shown only slightly declining on cycling, but it is still producing 140 mAh g- 1 after 100 cycles at 0. 1 C. Our results reveal the high quality and impressive cycling tenacity of SeO as cathode material in lithium-ion batteries.

Source link: https://ui.adsabs.harvard.edu/abs/2023JPS...55832547M/abstract


A perspective on influences of cathode material degradation on oxygen transport resistance in low Pt PEMFC

A large-scale industrial application of proton exchange membrane fuel cells is heavily dependent on both significant cost reduction and continued durability improvement. In this report, carbon support, electrocatalyst, ionomer, CCLs, as well as carbon material and hydrophobic polytetrafluoroethylene in GDLs are all investigated. It has been demonstrated that carbon corrosion in CCLs would result in pore structure destruction and impact ionomer delivery, thus impacting both the bulk and local oxygen transport behavior. Given the catalyst's degradation, a potential decrease in electrochemical active surface area increases the local oxygen transport resistance, although a decrease in active sites will result in a longer oxygen transport path.

Source link: https://ui.adsabs.harvard.edu/abs/2023NaRes..16..377L/abstract


W Modification of Nickel-Rich Ternary Cathode Material for Efficient Lithium-Ion Batteries

Nickel-rich layered cathode material, as one of the fastest-growing cathode materials, has gained a lot of attention in the nth-generation Li-ion batteries, due to its high specific energy, high operating capability, and long cycling life. As one of the fastest-growing cathode products, Nickel-rich layered cathode materials, as one of the fastest-growing cathode materials, as one of the fastest-growing catho LiNi 0. 65-x Co 0. 20 W x O 2 were synthesized by hydroxide coprecipitation and crystallization procedure, in an effort to fully investigate the obvious advantages of low-cost W doping cathode material on the crystalline morphology and electrochemical properties. The primary particle size can become significantly smaller as a result of doping appropriate content, which will help to maintain the crystal cathode material's stability and increase recycling efficiency, according to the reliable results. In addition, the W element was found in the crystal particle's lattice, which gives a small increase in lattice spacing and expands the Li + diffusion channels during charge/discharge cycles.

Source link: https://ui.adsabs.harvard.edu/abs/2023JElS..170a0523S/abstract


Evaluation of Cathode Materials with Lithium-Metal Anodes: Baseline Performance and Protocol Standardization of Coin Cells

To achieve reliable, one-to-one comparisons between various systems of interest, the collaborative evaluation of electrode materials from several research groups needs standard electrochemical testing procedures. [J. Electrochem. ] Electrochem. We then apply these methods to four commercially available cathode materials to develop benchmark performance measurements that can be used to analyze and analyze new cathode samples.

Source link: https://ui.adsabs.harvard.edu/abs/2023JElS..170a0507T/abstract


Enhanced high-rate cycling performance of LiMn 2 O 4 cathode materials by coating nano-TiO 2

LiMn 2 O 4 is regarded as a large-scale lithium battery cathode material, with low price and no pollution. Chemical precipitation was used to produce LiMn 2 O 4 precursors, and the precursors were coated to produce LiMn 2 O 4 / TiO 2 composites. At 0. 2 percent for pristine LiMn 2 O 4 / TiO 2, the initial discharge capacity of LiMn 2 O 4 / TiO 2 reached 106. 4 % after 100 cycles, down from 66. 5 percent for pristine LiMn 2 O 4 / TiO 2 at 66. 3 percent.

Source link: https://ui.adsabs.harvard.edu/abs/2023IJMR..114....7D/abstract


A novel hierarchical porous activated carbon-organic composite cathode material for high performance aqueous zinc-ion hybrid supercapacitors

Zinc-ion hybrid supercapacitors are one of the most promising electrochemical energy storage technologies due to their high energy density, environmental sustainability, low cost, and inherent safety. As a result, we have developed a novel energy storage system that converts a hierarchical porous activated carbon with redox-active organic compounds as an effective hybrid cathode material for ZIHSCs. Proposed RAZIHSCs demonstrated a lower self-discharge rate with a very low leakage current density as a result of the complex chemical reactions between Zn 2+ ions and H2 BNDI moiety in the composite cathode.

Source link: https://ui.adsabs.harvard.edu/abs/2023JPS...55732551P/abstract


Corrosion Behavior of Cobalt Oxide and Lithium Carbonate on Mullite–Cordierite Saggar Used for Lithium Battery Cathode Material Sintering

GriGris ceramic saggar, a form of essential consumable material used in the production process of LiCoO2 that can be easily degraded during application, is a primary consumable component used in Mullite's U2013cordierite ceramic saggar. To determine erosion reactants related to an increase in the number of recycled saggars, we investigated the high-temperature solid-state reactions between saggar powder and lithium carbonate or cobalt oxide. The results of a time-of-flight secondary ion mass spectrometric analysis indicate that the maximum erosion penetration of lithium can reach 2 mm. The key phases were lithium aluminate and lithium silicate when enough lithium carbonate reacted, lithium aluminate and lithium silicate. Our findings may contribute to improving saggar and upgrading waste saggar recycling techniques.

Source link: https://ui.adsabs.harvard.edu/abs/2023Mate...16..653S/abstract

* Please keep in mind that all text is summarized by machine, we do not bear any responsibility, and you should always check original source before taking any actions

* Please keep in mind that all text is summarized by machine, we do not bear any responsibility, and you should always check original source before taking any actions