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Acid (Band) - Astrophysics Data System

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Last Updated: 12 October 2021

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Two novel Pb(II) coordination polymers (CPs) based on 4-(4-oxopyridin-1(4H)-yl) and 3-(4-oxopyridin-1(4H)-yl) phthalic acid: Band gaps, structures, and their photoelectrocatalytic properties in CO2-saturated system

Based on 4- phthalic acid and 3- phthalic acid, two novel Pb sychronisation polymers formulated as [Pb4Cl4 · 2 · H2O] n, [Pb3Cl4 · L2 · H2O] n were solvothermally synthesized and characterized by single-crystal X-ray diffraction. Both novel Pb CPs possessed various structures. The photoelectrocatalytic performance of the two CPs towards CO2 decrease were evaluated by photocurrent responses at different used potentials. The photoelectrocatalytic efficiency of CP 2 was superior to that of CP 1 owing to the well-matched CB position of CP 2 and CO2 reduction potentials at the called for potential of -1. 4 V vs SCE. Furthermore, the photoelectrolytic experiment were executed 1 h in the CO2-saturated 0. 2 M Na2SO4 option at the needed possibility of -1. 4 V vs SCE with and without illumination, and we originally demonstrated the impact of noticeable light in the CO2-saturated photoelectrocatalytic dimension system and the reason of security in 1 h chronoamperometry.

Source link: https://ui.adsabs.harvard.edu/abs/2018JSSCh.261...43Y/abstract

* Please keep in mind that all text is summarized by machine, we do not bear any responsibility, and you should always check original source before taking any actions

* Please keep in mind that all text is summarized by machine, we do not bear any responsibility, and you should always check original source before taking any actions